A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Electrosynthesis and characterisation of poly(paraphenylene vinylene C-60) films
Tekijät: Kvarnstrom C, Kulovaara H, Damlin P, Ivaska A
Kustantaja: ELSEVIER SCIENCE SA
Julkaisuvuosi: 2003
Lehti:: Synthetic Metals
Tietokannassa oleva lehden nimi: SYNTHETIC METALS
Lehden akronyymi: SYNTHETIC MET
Vuosikerta: 135
Numero: 1-3
Aloitussivu: 783
Lopetussivu: 784
Sivujen määrä: 2
ISSN: 0379-6779
DOI: https://doi.org/10.1016/S0379-6779(02)00857-3
Tiivistelmä
The electrochemical reductive polymerization of a co-polymer of phenylene vinylene units and C-60 was studied. The fullerene is introduced into the polymer synthesis as a film on the electrode substrate. During reduction the film is dissolved and the reduced fullerene species interact with the PPV precursor in solution and as a result a film is formed on the substrate. The coupling reaction between the reduced species should lead to a material where the fullerene units are incorporated into the main polymer chain. The films are characterised by cyclic voltammetry and by FTIR and Raman spectroscopy.
The electrochemical reductive polymerization of a co-polymer of phenylene vinylene units and C-60 was studied. The fullerene is introduced into the polymer synthesis as a film on the electrode substrate. During reduction the film is dissolved and the reduced fullerene species interact with the PPV precursor in solution and as a result a film is formed on the substrate. The coupling reaction between the reduced species should lead to a material where the fullerene units are incorporated into the main polymer chain. The films are characterised by cyclic voltammetry and by FTIR and Raman spectroscopy.