A1 Refereed original research article in a scientific journal

Characterization of electrochemically synthesized PPV by in situ FTIR-ATR and resonant Raman spectroscopy




AuthorsDamlin P, Kvarnstrom C, Kulovaara H, Ivaska A

PublisherELSEVIER SCIENCE SA

Publication year2003

Journal:Synthetic Metals

Journal name in sourceSYNTHETIC METALS

Journal acronymSYNTHETIC MET

Volume135

Issue1-3

First page 309

Last page310

Number of pages2

ISSN0379-6779

DOIhttps://doi.org/10.1016/S0379-6779(02)00588-X


Abstract
In this work the electrochemical synthesis and the redox reactions (both n- and p-doping) of poly(paraphenylene vinylene) (PPV) have been studied in situ by Fourier Transform Infrared (FTIR) spectroscopy using the attenuated total reflection (ATR) method and by resonant Raman spectroscopy. During electrochemical polymerization a growth of bands assigned to PPV was observed both in FTIR and Raman spectra. The charging-discharging reaction of the PPV films showed reversible spectral changes.



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