A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Hydrodeoxygenation of vanillin over carbon supported metal catalysts
Tekijät: J.L. Santos, M. Alda-Onggar, V. Fedorov, M. Peurla, K. Eränen, P. Mäki-Arvela, M.Á. Centeno, D. Yu. Murzin
Kustantaja: ELSEVIER SCIENCE BV
Julkaisuvuosi: 2018
Journal: Applied Catalysis A: General
Tietokannassa oleva lehden nimi: APPLIED CATALYSIS A-GENERAL
Lehden akronyymi: APPL CATAL A-GEN
Vuosikerta: 561
Aloitussivu: 137
Lopetussivu: 149
Sivujen määrä: 13
ISSN: 0926-860X
eISSN: 1873-3875
DOI: https://doi.org/10.1016/j.apcata.2018.05.010
Tiivistelmä
Different carbon supported metal catalysts were synthesized, and characterized with various physico-chemical methods and tested in vanillin hydrodeoxygenation under 30 bar total pressure in water as a solvent at 100 degrees C. The catalysts exhibited high specific surface area and the metal dispersion decreased in following order: Pt/ C > Pd/C > Au/C > Rh/C > Ru/C. The most active catalyst was Pd/C followed by Ru/C. Vanillin hydrodeoxygenation proceeded via hydrogenation forming vanillyl alcohol further to its hydrogenolysis forming p-creosol. Both hydrogenation and hydrogenolysis were promoted by Pd/C, which exhibited rather high dispersion. The highest selectivity to p-creosol, 95% at complete vanillin conversion, was obtained with Pd/C. Kinetic modelling of vanillyl alcohol selectivity as a function of vanillin conversion was performed.
Different carbon supported metal catalysts were synthesized, and characterized with various physico-chemical methods and tested in vanillin hydrodeoxygenation under 30 bar total pressure in water as a solvent at 100 degrees C. The catalysts exhibited high specific surface area and the metal dispersion decreased in following order: Pt/ C > Pd/C > Au/C > Rh/C > Ru/C. The most active catalyst was Pd/C followed by Ru/C. Vanillin hydrodeoxygenation proceeded via hydrogenation forming vanillyl alcohol further to its hydrogenolysis forming p-creosol. Both hydrogenation and hydrogenolysis were promoted by Pd/C, which exhibited rather high dispersion. The highest selectivity to p-creosol, 95% at complete vanillin conversion, was obtained with Pd/C. Kinetic modelling of vanillyl alcohol selectivity as a function of vanillin conversion was performed.
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