High Resolution Gas Phase IR Spectroscopy Instrumentation




Jyrki K. Kauppinen, Jari O. Partanen

John C. Lindon, George E. Tranter, David Koppenaal

3.

2017

Encyclopedia of Spectroscopy and Spectrometry

ENCYCLOPEDIA OF SPECTROSCOPY AND SPECTROMETRY, 3RD EDITION, VOL 2: G-M

65

74

10

978-0-12-803224-4

DOIhttps://doi.org/10.1016/B978-0-12-803224-4.00340-X(external)



The definition of high resolution in IR spectroscopy has been changing with time. In this article, the limit of high resolution is defined as 0.1 cm-1. This is the full width at half height (FWHH) of the line; in other terms the higher the resolution, the smaller the FWHH. In history, grating and even prism spectrometers, which have a lower resolution than 0.1 cm-1, have also been regarded as high-resolution instruments, but the development of spectroscopic instrumentation has pushed the limit of high resolution towards smaller FWHH. Nowadays, high-resolution IR spectra are generally recorded by Fourier-transform IR (FT-IR) spectrometers, or by laser spectrometers. This article focuses on the last two types of spectrometers.



Last updated on 2024-26-11 at 19:30