A1 Refereed original research article in a scientific journal

Oxidomolybdenum(VI) complexes with aminoalcohol bis(phenolate) [O,N,O,O '] ligands: Synthesis and catalytic studies



Authors: Hakala J, Sillanpaa R, Lehtonen A

Publisher: ELSEVIER SCIENCE BV

Publication year: 2012

Journal: Inorganic Chemistry Communications

Journal name in source: INORGANIC CHEMISTRY COMMUNICATIONS

Journal acronym: INORG CHEM COMMUN

Volume: 21

First page : 21

Last page: 23

Number of pages: 3

ISSN: 1387-7003

DOI: https://doi.org/10.1016/j.inoche.2012.03.043


Abstract
Oxidomolybdenum(VI) complex [MoOCl(L-n)] with a tetradentate O3N-type aminoalcohol bis(phenol) was prepared as two separable isomers. These complexes can catalyse the epoxidation of cis-cyclooctene and sulphoxidation of tolyl methyl sulphide as well as the oxotransfer reaction between PPh3 and DMSO. (C) 2012 Elsevier B.V. All rights reserved.



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