An optical and electrochemical anion sensor of F- investigated by UV-vis, H-1 NMR and cyclic voltammetry

: Li JW, Lin H, Jiang P, Lin HK

Publisher: SPRINGER

: 2008

: Journal of Inclusion Phenomena and Macrocyclic Chemistry

: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY

: J INCL PHENOM MACRO

: 62

: 3-4

: 209

: 213

: 5

: 1388-3127

DOI: https://doi.org/10.1007/s10847-008-9458-9

A new anion receptor: 1,1'-di-(2',4'-di-nitrophenylhydrazino-beta-carbonyl)-ferrocene (1) based on ferrocene has been designed and synthesized as a highly colorimetric and electrochemical sensitive sensor for F-. The binding mode with F- was further investigated by UV-vis titration and 1H NMR titration experiments. In addition, the cyclic voltammetry (CV) was performed to discuss the electrochemical sensing for F-.

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