An "Ingredients" Approach to Functional Self-Synthesizing Materials: A Metal-Ion-Selective, Multi-Responsive, Self-Assembled Hydrogel
: Li JW, Cvrtila I, Colomb-Delsuc M, Otten E, Otto S
Publisher: WILEY-V C H VERLAG GMBH
: 2014
: Chemistry - A European Journal
: CHEMISTRY-A EUROPEAN JOURNAL
: CHEM-EUR J
: 20
: 48
: 15709
: 15714
: 6
: 0947-6539
DOI: https://doi.org/10.1002/chem.201404977
New methodology for making novel materials is highly desirable. Here, an "ingredients" approach to functional self-assembled hydrogels was developed. By designing a building block to contain the right ingredients, a multi-responsive, self-assembled hydrogel was obtained through a process of template-induced self-synthesis in a dynamic combinatorial library. The system can be switched between gel and solution by light, redox reactions, pH, temperature, mechanical energy and sequestration or addition of MgII salt.