A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Reactions of tris (1,2-ethanediolato)tungsten (VI) with phenyl acetates. X-ray structures of three products
Tekijät: Lehtonen A, Sillanpaa R
Kustantaja: PERGAMON-ELSEVIER SCIENCE LTD
Julkaisuvuosi: 1998
Lehti:: Polyhedron
Tietokannassa oleva lehden nimi: POLYHEDRON
Lehden akronyymi: POLYHEDRON
Vuosikerta: 18
Numero: 1-2
Aloitussivu: 175
Lopetussivu: 179
Sivujen määrä: 5
ISSN: 0277-5387
DOI: https://doi.org/10.1016/S0277-5387(98)00281-2
Tiivistelmä
Tungsten(VI) complex [W(eg)(3)] (eg=ethanediolate dianion) reacts with phenyl acetates leading to the displacement of one or three diolato ligands. Two types of phenoxides, [W(O-C6H4R-4)(6)] (R=H, Me, Cl) and [W(eg)(2)(OC6H3R2'-2,6)(2)] (R' = Me, Pr-i) are formed, depending on the nature of phenyl group. The X-ray crystal structure determinations of [W(OC6H5)(6)], [W(eg)(2)(OC6H3Me2- 2,6)(2)] and [W(eg)(2)((OC6H3Pr2)-Pr-i-2,6)(2)] confirmed the obtained compounds. (C) 1998 Elsevier Science Ltd. All rights reserved.
Tungsten(VI) complex [W(eg)(3)] (eg=ethanediolate dianion) reacts with phenyl acetates leading to the displacement of one or three diolato ligands. Two types of phenoxides, [W(O-C6H4R-4)(6)] (R=H, Me, Cl) and [W(eg)(2)(OC6H3R2'-2,6)(2)] (R' = Me, Pr-i) are formed, depending on the nature of phenyl group. The X-ray crystal structure determinations of [W(OC6H5)(6)], [W(eg)(2)(OC6H3Me2- 2,6)(2)] and [W(eg)(2)((OC6H3Pr2)-Pr-i-2,6)(2)] confirmed the obtained compounds. (C) 1998 Elsevier Science Ltd. All rights reserved.
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