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REACTIONS OF DICHLOROBIS(2,3-DIMETHYLBUTANE-2,3-DIOLATO)TUNGSTEN(VI) WITH WATER AND ALCOHOLS
Tekijät: LEHTONEN A, SILLANPAA R
Kustantaja: ROYAL SOC CHEMISTRY
Julkaisuvuosi: 1995
Lehti:: Dalton Transactions
Tietokannassa oleva lehden nimi: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Lehden akronyymi: J CHEM SOC DALTON
Numero: 16
Aloitussivu: 2701
Lopetussivu: 2704
Sivujen määrä: 4
ISSN: 0300-9246
DOI: https://doi.org/10.1039/dt9950002701
Tiivistelmä
A tungsten (VI) complex [WCl2(pin)(2)] 1 [H(2)pin = pinacol (2,3-dimethylbutane-2.3-diol)l reacted with water forming dimeric [W2O3(pin)(2)(Hpin)(2)]. but in the presence of tripropylamine [(NPr3H)(2)Cl](2)[W6O19] 2 was formed. The reaction of 1 with H(2)pin led to [W(pin)(3)] and with phenol (PhOH) to [W(pin)(2)(OPh)(2)] 3. The structures of complexes 2 and 3 were confirmed by X-ray methods. Compound 2 is made up of the known [W6O19](2-) anion and two [NPr3H ... Cl-... HNPr3](+) cations. Complex 3 is formed of monomeric [W(pin)(2)(OPh)(2)] molecules in which the W atom is octahedrally surrounded by six oxygen atoms.
A tungsten (VI) complex [WCl2(pin)(2)] 1 [H(2)pin = pinacol (2,3-dimethylbutane-2.3-diol)l reacted with water forming dimeric [W2O3(pin)(2)(Hpin)(2)]. but in the presence of tripropylamine [(NPr3H)(2)Cl](2)[W6O19] 2 was formed. The reaction of 1 with H(2)pin led to [W(pin)(3)] and with phenol (PhOH) to [W(pin)(2)(OPh)(2)] 3. The structures of complexes 2 and 3 were confirmed by X-ray methods. Compound 2 is made up of the known [W6O19](2-) anion and two [NPr3H ... Cl-... HNPr3](+) cations. Complex 3 is formed of monomeric [W(pin)(2)(OPh)(2)] molecules in which the W atom is octahedrally surrounded by six oxygen atoms.
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