A2 Refereed review article in a scientific journal

ss(LG) values in mechanistic studies on the transesterification of RNA models and their application in a metal ion complex promoted transesterification



Authors: Heidi Korhonen, Nicholas H Williams, Satu Mikkola

Publisher: WILEY-BLACKWELL

Publication year: 2013

Journal: Journal of Physical Organic Chemistry

Journal name in source: JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Journal acronym: J PHYS ORG CHEM

Number in series: 2

Volume: 26

Issue: 2

First page : 182

Last page: 186

Number of pages: 5

ISSN: 0894-3230

DOI: https://doi.org/10.1002/poc.2942


Abstract
Studies on the mechanism of transesterification reactions of nucleoside 3'-phosphoesters using beta LG values as a mechanistic tool are discussed in this mini review. Our recent observation that a dinuclear metal ion complex enhances both the cleavage and isomerisation is discussed in the light of previous studies. Copyright (C) 2012 John Wiley & Sons, Ltd.



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