Quadrupole coupling in ammonium metaperiodate at low temperature
: Segel SL, Brown RJC, Ylinen EE, Ingman LP, Bastow TJ
Publisher: VERLAG Z NATURFORSCH
: 2002
Zeitschrift fur Naturforschung a
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
: Z NATURFORSCH A
: 57
: 8
: 661
: 662
: 2
: 0932-0784
The temperature dependences of the I-127 nuclear quadrupole coupling in NH4IO4 and in ND4IO4 are reported. In each salt, the quadrupole coupling decreases to a very small value at low temperatures, and, in the case of ND4IO4 passes through zero and changes sign at 87 K.