A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Preparation and crystal structures of oxoosmium(VI) diolato complexes
Tekijät: Lehtonen A, Jokela J, Edwards PG, Sillanpaa R
Kustantaja: ROYAL SOC CHEMISTRY
Julkaisuvuosi: 1999
Lehti:: Dalton Transactions
Tietokannassa oleva lehden nimi: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Lehden akronyymi: J CHEM SOC DALTON
Numero: 16
Aloitussivu: 2785
Lopetussivu: 2788
Sivujen määrä: 4
ISSN: 0300-9246
DOI: https://doi.org/10.1039/a903042e
Tiivistelmä
Reaction of OsO4 with one equivalent of PPh3 in the presence of the tertiary diols, 2,3-dimethyl-2,3-butanediol (H(2)pin) and 1,1'-bicyclohexane-1,1'-diol (H(2)bicy), afforded the new oxoosmium(VI) complexes [OsO(diol)(2)]. The molecular structures of [OsO(pin)(2)], [OsO(bicy)(2)] and its adduct [OsO(bicy)(2)]. H(2)bicy . PPh3O were determined by X-ray crystallography.
Reaction of OsO4 with one equivalent of PPh3 in the presence of the tertiary diols, 2,3-dimethyl-2,3-butanediol (H(2)pin) and 1,1'-bicyclohexane-1,1'-diol (H(2)bicy), afforded the new oxoosmium(VI) complexes [OsO(diol)(2)]. The molecular structures of [OsO(pin)(2)], [OsO(bicy)(2)] and its adduct [OsO(bicy)(2)]. H(2)bicy . PPh3O were determined by X-ray crystallography.
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