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REDOX SWITCHING MECHANISM OF POLYTHIOPHENES
Tekijät: VISY C, LUKKARI J, KANKARE J
Kustantaja: ELSEVIER SCIENCE SA LAUSANNE
Julkaisuvuosi: 1993
Lehti:: Synthetic Metals
Tietokannassa oleva lehden nimi: SYNTHETIC METALS
Lehden akronyymi: SYNTHETIC MET
Vuosikerta: 55
Numero: 2-3
Aloitussivu: 1620
Lopetussivu: 1625
Sivujen määrä: 6
ISSN: 0379-6779
Tiivistelmä
The redox switching mechanism of conducting polymers is not yet clarified in every respect, the problem of interpretation of the transformation between the insulating and conducting forms of the polymeric film is not yet unambigously solved[1-16]. It is thought that spectroelectrochemical studies on the anodic and cathodic switching of different poly(3'-substituted 2,2':5',2''-terthiophenes) (Fig.1.) could give further information about the processes occurring during the transformation between their insulating and conductive forms owing to a hopefully more regular structure compared to polythiophene considering the molecular level effect of the substituent on the properties of the polymer[2,12].
The redox switching mechanism of conducting polymers is not yet clarified in every respect, the problem of interpretation of the transformation between the insulating and conducting forms of the polymeric film is not yet unambigously solved[1-16]. It is thought that spectroelectrochemical studies on the anodic and cathodic switching of different poly(3'-substituted 2,2':5',2''-terthiophenes) (Fig.1.) could give further information about the processes occurring during the transformation between their insulating and conductive forms owing to a hopefully more regular structure compared to polythiophene considering the molecular level effect of the substituent on the properties of the polymer[2,12].
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