A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Oxidomolybdenum(VI) complexes with atrane-type [O3N] ligands
Tekijät: Lauren E, Kivela H, Hanninen M, Lehtonen A
Kustantaja: PERGAMON-ELSEVIER SCIENCE LTD
Julkaisuvuosi: 2009
Lehti:Polyhedron
Tietokannassa oleva lehden nimiPOLYHEDRON
Lehden akronyymi: POLYHEDRON
Vuosikerta: 28
Numero: 18
Aloitussivu: 4051
Lopetussivu: 4055
Sivujen määrä: 5
ISSN: 0277-5387
DOI: https://doi.org/10.1016/j.poly.2009.09.033
Tiivistelmä
Dioxomolybdenum(VI) complex [MoO2Cl2(dmso)(2)] reacts with a series of tetradentate O3N-type amino-alcohol-bisphenol ligands to form oxomolybdenum(VI) complexes of type [MoOCl(L-n)]. The reaction of H3L1 produces [MoOCl(L-1)] as two separable isomers, whereas the reaction of H3L2 or H3L3 yields a single product. The X-ray analyses of cis- and trans-[MoOCl(L-1)] reveal that the complexes are formed of monomeric molecules. The ligands have tetradentate coordination through three oxygen donors and one nitrogen donor, which is located trans to the terminal oxo group. The sixth coordination site is occupied by a chloro ligand. (C) 2009 Elsevier Ltd. All rights reserved.
Dioxomolybdenum(VI) complex [MoO2Cl2(dmso)(2)] reacts with a series of tetradentate O3N-type amino-alcohol-bisphenol ligands to form oxomolybdenum(VI) complexes of type [MoOCl(L-n)]. The reaction of H3L1 produces [MoOCl(L-1)] as two separable isomers, whereas the reaction of H3L2 or H3L3 yields a single product. The X-ray analyses of cis- and trans-[MoOCl(L-1)] reveal that the complexes are formed of monomeric molecules. The ligands have tetradentate coordination through three oxygen donors and one nitrogen donor, which is located trans to the terminal oxo group. The sixth coordination site is occupied by a chloro ligand. (C) 2009 Elsevier Ltd. All rights reserved.
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