Room temperature phosphorescence emission in fully aqueous medium induced by injection of hot electrons into an electrolyte solution

: Kulmala S, Ala-Kleme T

Publisher: ELSEVIER SCIENCE BV

: 1997

Analytica Chimica Acta

: ANALYTICA CHIMICA ACTA

: ANAL CHIM ACTA

: 355

: 1

: 5

: 0003-2670

DOI: https://doi.org/10.1016/S0003-2670(97)81605-4

Tunnel-emitted hot electrons induce the triplet state emission of the ligand of an aromatic Gd(III) chelate while the corresponding Tb(III) chelate shows a metal-centred emission at cathodically pulse-polarised oxide-covered aluminum electrodes in fully aqueous solutions at room temperature. (C) 1997 Elsevier Science B.V.