Aminobisphenolate supported tungsten disulphido and dithiolene complexes




Salojarvi E, Peuronen A, Sillanpaa R, Damlin P, Kivela H, Lehtonen A

PublisherRoyal Soc Chemistry

2015

Dalton Transactions

DALTON TRANSACTIONS

Dalton T

44

20

9409

9416

8

1477-9226

DOIhttps://doi.org/10.1039/c5dt00995b(external)



Dioxotungsten(VI) complexes with tetradentate amino bisphenolates were converted into the corresponding C-s-symmetric amino bisphenolate disulphido complexes by a reaction with either Lawesson's reagent or P2S5. Further reaction with diethyl acetylenedicarboxylate leads to the formation of diamagnetic tungsten(IV) dithiolene compounds. The syntheses, crystal structures, spectroscopic and electrochemical characterization of such disulphido and dithiolene complexes are presented.




Last updated on 2024-26-11 at 14:39