Refereed journal article or data article (A1)

Aminobisphenolate supported tungsten disulphido and dithiolene complexes




List of Authors: Salojarvi E, Peuronen A, Sillanpaa R, Damlin P, Kivela H, Lehtonen A

Publisher: Royal Soc Chemistry

Publication year: 2015

Journal: Dalton Transactions

Journal name in source: DALTON TRANSACTIONS

Journal acronym: Dalton T

Volume number: 44

Issue number: 20

Number of pages: 8

ISSN: 1477-9226

DOI: http://dx.doi.org/10.1039/c5dt00995b


Abstract

Dioxotungsten(VI) complexes with tetradentate amino bisphenolates were converted into the corresponding C-s-symmetric amino bisphenolate disulphido complexes by a reaction with either Lawesson's reagent or P2S5. Further reaction with diethyl acetylenedicarboxylate leads to the formation of diamagnetic tungsten(IV) dithiolene compounds. The syntheses, crystal structures, spectroscopic and electrochemical characterization of such disulphido and dithiolene complexes are presented.



Last updated on 2021-24-06 at 09:20