A NEW SYNTHETIC ROUTE TO CIS-DICHLOROBISDIOLATOTUNGSTEN(VI) COMPLEXES

: LEHTONEN A, SILLANPAA R

Publisher: PERGAMON-ELSEVIER SCIENCE LTD

: 1995

Polyhedron

POLYHEDRON

: POLYHEDRON

: 14

: 3

: 455

: 457

: 3

: 0277-5387

DOI: https://doi.org/10.1016/0277-5387(94)00422-B

The substitution of a diolato ligand by two chlorides around a tungsten(VI) centre was carried out by thionyl chloride in dichloromethane. The preparation and structure of cis-[WCl2(pin)(2)] (pin = 2,3-dimethyl-2,3-butanediolato) is described.