Up-conversion luminescence of the NaYF4:Yb3+,Er3+ nanomaterials prepared with the solvothermal synthesis

: Palo E, Pihlgren L, Tuomisto M, Laihinen T, Hyppanen I, Kankare J, Lastusaari M, Soukka T, Swart HC, Holsa J

Publisher: ELSEVIER SCIENCE BV

: 2016

: Optical Materials

: OPTICAL MATERIALS

: OPT MATER

: 59

: 49

: 54

: 6

: 0925-3467

: 1873-1252

DOI: https://doi.org/10.1016/j.optmat.2016.02.043

Up-converting NaYF4:Yb3+,Er3+ (x(yb): 0.20, x(Er): 0.02) nanomaterials were prepared with a microwave assisted solvothermal synthesis to study how the synthesis parameters affect the structure and up conversion luminescence of the materials and thus their usability as labels in biomedical applications. The purity of the materials was studied with Fourier transform infra-red (FT-IR) spectroscopy and the particle size and morphology with transmission electron microscopy (TEM). The crystal structure was characterized with X-ray powder diffraction (XPD) and the crystallite sizes were calculated with the Scherrer formula. Up-conversion luminescence and luminescence decays were studied with near infrared (NIR) laser excitation at 970 nm.The presence of the oleic acid was observed in the FT-IR spectra. The TEM images showed small quasi spherical nanoparticles as well as long nanorods. The XPD measurements revealed that both cubic and hexagonal forms of NaYF4 were present in the materials. The crystallite sizes ranged from ca. 20 to over 150 nm for the cubic and hexagonal phases, respectively. The characteristic up-conversion luminescence of Era(3+) in red (640-685 nm; F-4(9/2) -> I-4(15/2)) and green (515-560 nm; H-2(11/2), S-4(3/2) -> I-4(15/2) transitions) wavelengths was observed. The most intense luminescence and the longest luminescence emission lifetime were obtained with the material annealed for 12 hat 177 degrees C with 1.8 MPa pressure due to the predominance of the well-crystallized hexagonal form of NaRF4 (R: Y, Yb, Er). (C) 2016 Elsevier B.V. All rights reserved.