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Luminometric Label Array for Quantification and Identification of Metal Ions
Tekijät: Pihlasalo S, Perez IM, Hollo N, Hokkanen E, Pahikkala T, Harma H
Kustantaja: AMER CHEMICAL SOC
Julkaisuvuosi: 2016
Journal: Analytical Chemistry
Tietokannassa oleva lehden nimi: ANALYTICAL CHEMISTRY
Lehden akronyymi: ANAL CHEM
Vuosikerta: 88
Numero: 10
Aloitussivu: 5271
Lopetussivu: 5280
Sivujen määrä: 10
ISSN: 0003-2700
DOI: https://doi.org/10.1021/acs.analchem.6b00453
Tiivistelmä
Quantification and identification of metal ions has gained interest in drinking water and environmental analyses. We have developed a novel label array method for the quantification and identification of metal ions in drinking water. This simple ready-to-go method is based on the nonspecific interactions of multiple unstable lanthanide chelates and nonantenna ligands with sample leading to a luminescence signal profile, unique to the sample components. The limit of detection at ppb concentration level and average coefficient of variation of 10% were achieved with the developed label array. The identification of 15 different metal ions including different oxidation states Cr3+/Cr6+, Cu+/Cu2+, Fe2+/Fe3+, and Pb2+/Pb4+ was demonstrated. Moreover, a binary mixture of Cu2+ and Fe3+ and ternary mixture of Cd2+, Ni2+, and Pb2+ were measured and individual ions were distinguished.
Quantification and identification of metal ions has gained interest in drinking water and environmental analyses. We have developed a novel label array method for the quantification and identification of metal ions in drinking water. This simple ready-to-go method is based on the nonspecific interactions of multiple unstable lanthanide chelates and nonantenna ligands with sample leading to a luminescence signal profile, unique to the sample components. The limit of detection at ppb concentration level and average coefficient of variation of 10% were achieved with the developed label array. The identification of 15 different metal ions including different oxidation states Cr3+/Cr6+, Cu+/Cu2+, Fe2+/Fe3+, and Pb2+/Pb4+ was demonstrated. Moreover, a binary mixture of Cu2+ and Fe3+ and ternary mixture of Cd2+, Ni2+, and Pb2+ were measured and individual ions were distinguished.
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