A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
cis-Dioxomolybdenum(VI) complexes with tridentate and tetradentate Schiff base ligands. Preparation, structures and inhibition of aerial oxidation of aldehydes
Tekijät: Liimatainen J, Lehtonen A, Sillanpaa R
Kustantaja: PERGAMON-ELSEVIER SCIENCE LTD
Julkaisuvuosi: 2000
Lehti:Polyhedron
Tietokannassa oleva lehden nimiPOLYHEDRON
Lehden akronyymi: POLYHEDRON
Vuosikerta: 19
Numero: 9
Aloitussivu: 1133
Lopetussivu: 1138
Sivujen määrä: 6
ISSN: 0277-5387
DOI: https://doi.org/10.1016/S0277-5387(00)00368-5
Tiivistelmä
The synthesis and characterisation of foul monomeric cis-dioxomolybdenum(VI) complexes involving Schiff base ligands is described. Ligands were obtained by condensation of salicylaldehyde with substituted aminoethanols. [MoO2(acac)(2)] reacted with the prepared ligands forming six-coordinated cis-dioxoMo(VI) complexes. X-ray diffraction studies confirmed that ligands act in a tridentate manner and the sixth coordination site around Mo(VI) is occupied by methanol used as solvent. The complexes act as inhibitors in the oxidation of aldehydes by oxygen. (C) 2000 Elsevier Science Ltd All rights reserved.
The synthesis and characterisation of foul monomeric cis-dioxomolybdenum(VI) complexes involving Schiff base ligands is described. Ligands were obtained by condensation of salicylaldehyde with substituted aminoethanols. [MoO2(acac)(2)] reacted with the prepared ligands forming six-coordinated cis-dioxoMo(VI) complexes. X-ray diffraction studies confirmed that ligands act in a tridentate manner and the sixth coordination site around Mo(VI) is occupied by methanol used as solvent. The complexes act as inhibitors in the oxidation of aldehydes by oxygen. (C) 2000 Elsevier Science Ltd All rights reserved.
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