A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Characterisation of poly(3,4-ethylenedioxythiophene) films polymerised in aqueous media
Tekijät: Ahonen HJ, Lukkari J, Hellstrom T, Mattila J, Kankare J
Kustantaja: ELSEVIER SCIENCE SA
Julkaisuvuosi: 2001
Lehti:: Synthetic Metals
Tietokannassa oleva lehden nimi: SYNTHETIC METALS
Lehden akronyymi: SYNTHETIC MET
Vuosikerta: 119
Numero: 1-3
Aloitussivu: 119
Lopetussivu: 120
Sivujen määrä: 2
ISSN: 0379-6779
DOI: https://doi.org/10.1016/S0379-6779(00)01101-2
Tiivistelmä
Highly conducting poly(3,4-ethylenedioxythiophene) films have been electrosynthesised in aqueous medium. The highest in situ conductivity of the films obtained in pure aqueous medium was of the same order than with the films polymerised in organic solvents. The UV-Vis characterisation of the films showed that the average conjugation length of the polymer chains was affected only slightly by selecting water as the electrosynthesis medium. Furthermore, FTIR measurements indicated that no ring opening or overoxidation of the films had occurred in either media.
Highly conducting poly(3,4-ethylenedioxythiophene) films have been electrosynthesised in aqueous medium. The highest in situ conductivity of the films obtained in pure aqueous medium was of the same order than with the films polymerised in organic solvents. The UV-Vis characterisation of the films showed that the average conjugation length of the polymer chains was affected only slightly by selecting water as the electrosynthesis medium. Furthermore, FTIR measurements indicated that no ring opening or overoxidation of the films had occurred in either media.
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