A1 Refereed original research article in a scientific journal
SYNTHESIS AND CRYSTAL-STRUCTURES OF DINUCLEAR OXOTUNGSTEN(VI) DIOLATO COMPLEXES
Authors: LEHTONEN A, SILLANPAA R
Publisher: ROYAL SOC CHEMISTRY
Publication year: 1994
Journal:: Dalton Transactions
Journal name in source: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Journal acronym: J CHEM SOC DALTON
Issue: 14
First page : 2119
Last page: 2124
Number of pages: 6
ISSN: 0300-9246
DOI: https://doi.org/10.1039/dt9940002119
Abstract
Dinuclear complexes [W2O3L2(HL)2] [H2L = 2,3-dimethylbutane-2,3-diol (H2pin), trans-cycloheptane-1,2-diol (H2chpd) or trans-cyclooctane-1,2-diol (H2Cocd)] were prepared in high yield by hydrolysis of [W(eg)(pin)2] (H2eg = ethane-1,2-diolate), [W(chpd)3] and [W(cocd)3] in alcoholic solution. X-Ray diffraction studies showed that each tungsten(VI) ion is bonded to one diolate, one hydrogendiolate, one terminal and one bridging oxide ligand. Two tungsten-centred units are also linked together by intramolecular O...-O hydrogen bonds between the diolate and hydrogendiolate ligands. The geometry of the dinuclear unit is dependent on the nature of the diolate ligands.
Dinuclear complexes [W2O3L2(HL)2] [H2L = 2,3-dimethylbutane-2,3-diol (H2pin), trans-cycloheptane-1,2-diol (H2chpd) or trans-cyclooctane-1,2-diol (H2Cocd)] were prepared in high yield by hydrolysis of [W(eg)(pin)2] (H2eg = ethane-1,2-diolate), [W(chpd)3] and [W(cocd)3] in alcoholic solution. X-Ray diffraction studies showed that each tungsten(VI) ion is bonded to one diolate, one hydrogendiolate, one terminal and one bridging oxide ligand. Two tungsten-centred units are also linked together by intramolecular O...-O hydrogen bonds between the diolate and hydrogendiolate ligands. The geometry of the dinuclear unit is dependent on the nature of the diolate ligands.
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