A1 Vertaisarvioitu alkuperäisartikkeli tieteellisessä lehdessä
Etherification of 5-Hydroxymethylfurfural to a Biodiesel Component Over Ionic Liquid Modified Zeolites
Tekijät: Eero Salminen, Narendra Kumar, Pasi Virtanen, Mikko Tenho, Päivi Mäki-Arvela, Jyri-Pekka Mikkola
Kustantaja: SPRINGER/PLENUM PUBLISHERS
Kustannuspaikka: NEW YORK; 233 SPRING ST, NEW YORK, NY 10013 USA
Julkaisuvuosi: 2013
Journal: Topics in Catalysis
Tietokannassa oleva lehden nimi: Topics in Catalysis
Lehden akronyymi: Top.Catal.
Numero sarjassa: 9-10
Vuosikerta: 56
Numero: 9-10
Aloitussivu: 765
Lopetussivu: 769
Sivujen määrä: 5
ISSN: 1022-5528
DOI: https://doi.org/10.1007/s11244-013-0035-0
Tiivistelmä
In this work, ionic liquid (IL) modified H-Beta zeolites were prepared and the physicochemical properties of the catalysts were investigated. IL modified zeolites were applied in 5-hydroxymethylfurfural (HMF) etherification to tert-butoxymethylfurfural (tBMF) which is a potential (bio)diesel component. The best catalyst, IL-H-Beta-25, yielded at BMF selectivity of 76 % corresponding to a HMF conversion of 46 %.
In this work, ionic liquid (IL) modified H-Beta zeolites were prepared and the physicochemical properties of the catalysts were investigated. IL modified zeolites were applied in 5-hydroxymethylfurfural (HMF) etherification to tert-butoxymethylfurfural (tBMF) which is a potential (bio)diesel component. The best catalyst, IL-H-Beta-25, yielded at BMF selectivity of 76 % corresponding to a HMF conversion of 46 %.