A1 Refereed original research article in a scientific journal
Nanocrystalline Sr2FeMoO6 prepared by citrate-gel method
Authors: Raittila J, Salminen T, Suominen T, Schlesier K, Paturi P
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Publication year: 2006
Journal:Journal of Physics and Chemistry of Solids
Journal name in sourceJOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
Journal acronym: J PHYS CHEM SOLIDS
Volume: 67
Issue: 8
First page : 1712
Last page: 1718
Number of pages: 7
ISSN: 0022-3697
DOI: https://doi.org/10.1016/j.jpcs.2006.03.009
Abstract
Double perovskite Sr2FeMoO6 powders with small crystallite size have been synthesised with citrate-gel method. The starting solution pH was varied between 1.5 and 9.0 resulting in large differences in the phase composition and ordering of B'/B '' sites. The samples prepared at 975 degrees C had crystallite sizes under 40 nm whereas crystallite sizes of the samples prepared at 1050 degrees C were between 78 and 239 nm. The XRD patterns were refined with spacegroup I 4/m, which gave good results for both batches, although clearly better results were obtained with monoclinic P 2(1)/n spacegroup for the 975 degrees C batch. The ordering and the saturation magnetization agreed well with each other after treatment at 1050 degrees C, but the samples prepared at 975 degrees C had a strongly reduced saturation magnetization from that given by the ordering. (c) 2006 Elsevier Ltd. All rights reserved.
Double perovskite Sr2FeMoO6 powders with small crystallite size have been synthesised with citrate-gel method. The starting solution pH was varied between 1.5 and 9.0 resulting in large differences in the phase composition and ordering of B'/B '' sites. The samples prepared at 975 degrees C had crystallite sizes under 40 nm whereas crystallite sizes of the samples prepared at 1050 degrees C were between 78 and 239 nm. The XRD patterns were refined with spacegroup I 4/m, which gave good results for both batches, although clearly better results were obtained with monoclinic P 2(1)/n spacegroup for the 975 degrees C batch. The ordering and the saturation magnetization agreed well with each other after treatment at 1050 degrees C, but the samples prepared at 975 degrees C had a strongly reduced saturation magnetization from that given by the ordering. (c) 2006 Elsevier Ltd. All rights reserved.
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