Refereed journal article or data article (A1)
Aminobisphenolate supported tungsten disulphido and dithiolene complexes
List of Authors: Salojarvi E, Peuronen A, Sillanpaa R, Damlin P, Kivela H, Lehtonen A
Publisher: Royal Soc Chemistry
Publication year: 2015
Journal: Dalton Transactions
Journal name in source: DALTON TRANSACTIONS
Journal acronym: Dalton T
Volume number: 44
Issue number: 20
Start page: 9409
End page: 9416
Number of pages: 8
ISSN: 1477-9226
DOI: http://dx.doi.org/10.1039/c5dt00995b
Dioxotungsten(VI) complexes with tetradentate amino bisphenolates were converted into the corresponding C-s-symmetric amino bisphenolate disulphido complexes by a reaction with either Lawesson's reagent or P2S5. Further reaction with diethyl acetylenedicarboxylate leads to the formation of diamagnetic tungsten(IV) dithiolene compounds. The syntheses, crystal structures, spectroscopic and electrochemical characterization of such disulphido and dithiolene complexes are presented.